Neopentyl glycol diglycidyl ether (cas ) msds download -
Neopentyl glycol diglycidyl ether (cas )
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print date 07/06/2007
Revision Date 06/03/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
HELOXY?? Modifier 68
Trade name :
Product code : L150
MSDS Number : 1369
Product Type : Viscosity modifier
Manufacturer, importer, : Hexion Specialty Chemicals, Inc.
supplier P. O. Box 4500
Houston TX 77210
Contact person :
Telephone : General Information:
(832) 486-6700
Emergency telephone:
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Human health hazards : May be harmful if swallowed. May be irritating to the eyes and
skin. May cause skin sensitization.
Safety hazards : Material will not burn unless preheated.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Weight %
2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]
SECTION 4. FIRST AID MEASURES
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
General advice : Get medical attention immediately if symptoms occur.
Inhalation : Remove victim to fresh air and provide oxygen if breathing is
difficult. Get medical attention.
Skin contact : Remove contaminated clothing/shoes and wipe excess from
skin. Flush skin with water. Follow by washing with soap and
water. In case of inflammation (redness, irritation, ...) obtain
medical attention. Show this sheet to the doctor.
Eye contact : Flush eyes with plenty of water for 15 minutes while holding
eyelids open. Rest eyes for 30 minutes. If redness, burning,
blurred vision or swelling persist, consult a physician.
Ingestion : Do not induce vomiting. Have victim rinse out mouth with water,
then drink sips of water to remove taste from mouth. In general,
no treatment is necessary unless large quantites of product are
ingested. However, get medical advice.
Notes to physician
Symptoms : Irritation of the skin
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Use water fog, foam, dry chemical or carbon dioxide.
Specific hazards during fire : Material will not burn unless preheated.
Evacuate the area of all non-essential personnel. Containers
exposed to intense heat from fires should be cooled with water
to prevent vapor pressure buildup which could result in container
rupture. Container areas exposed to direct flame contact should
be cooled with large quantities of water as needed to prevent
weakening of container structure. Cool fire exposed containers
with water.
Special protective : Do not enter confined fire space without full bunker gear (helmet
equipment for fire-fighters with face shield, bunker coats, gloves and rubber boots).
including a positive pressure NIOSH approved self-contained
breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
Personal precautions : May burn although not readily ignitable.
Use cautious judgement when cleaning up large spills.
Shut off leaks, if possible without personal risk.
Environmental precautions : Dike and contain.
Contain run-off and dispose of properly.
Remove contaminated soil to remove contaminated trace
Prevent from entering into drains, ditches or rivers.
Clean-up methods - small : Take up with an absorbent material and place in non-leaking
spillage containers.
Seal tightly for proper disposal.
Clean-up methods - large : Remove with vacuum trucks or pump to storage/salvage
spillage vessels.
Soak up residue with an absorbent such as clay, sand or other
place in non-leaking containers for proper
Flush area with water to remove trace residue.
Additional advice : Notify authorities if any exposures to the general public or
environment occurs or is likely to occur.
See Section 13 for information on disposal.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin, eyes and clothing Wash thoroughly
after handling. Containers, even those that have been emptied,
can contain hazardous product residues. Surfaces that are
sufficiently hot may ignite even liquid product in the absence of
sparks or flame. WARNING. May cause skin sensitization.
Wash with soap and water before eating, drinking, smoking,
applying cosmetics, or using toilet facilities. Launder
contaminated clothing before reuse. Contaminated leather
articles, including shoes, cannot be decontaminated and should
be destroyed to prevent reuse.
Requirements for storage : Store in a cool, dry place with adequate ventilation. Keep away
areas and containers from open flames and high temperatures. Keep containers
closed when not in use.
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective measures : Wear appropriate respirator and protective clothing.
Engineering measures : Adequate ventilation to control airborne concentrations.
Eye wash fountains and safety showers should be available for
emergency use.
: Use local exhaust ventilation.
Eye protection : Avoid contact with eyes.
Wear chemical goggles.
Skin and body protection : Avoid prolonged or repeated contact with skin.
Wear chemical-resistant gloves and other clothing as required to
minimize contact.
Respiratory protection : Avoid breathing vapor or mists.
Use a NIOSH-approved respirator as required to prevent
overexposure.
In accord with 29 CFR , the types of respirator(s) to be
considered include:
Air-Purifying Respirator for Organic Vapors.
Full-Face Supplied-Air Respirator.
Exposure Guidelines
Components with Regulation Exposure time Value Remarks
workplace control
parameters
Oxirane, ACGIH None established.
2,2'-[(2,2-dimethyl-1,3-pro
panediyl)bis(oxymethylene
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Colour : Colourless
Odour : Mild
Boiling point : & 300 ??F (& 300 ??F)
Flash point : & 93 ??C (& 199 ??F) (Setaflash)
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
Vapour pressure : & 1.33 mbar
Relative density : 1.05
Solubility in water : Negligible.
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Avoid high temperatures.
Materials to avoid : Can react vigorously with strong oxidizing agents, strong lewis
or mineral acid, and strong mineral and organic bases,
especially primary and secondary aliphatic amines.
Reaction with some curing agents may produce considerable
heat and possible violent decomposition.
Hazardous reactions : Stable under normal use conditions.
Hazardous polymerization will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : no data available
Expected to be of low toxicity, LD50 & 2000 mg/kg.
Acute dermal toxicity : Expected to be of low toxicity, LD50 & 2000 mg/kg.
Acute inhalation toxicity : no data available
Chronic Health Hazard
Components Concentration Regulation Value Remarks
Oxirane, 100 % US. IARC Monographs on This
2,2'-[(2,2-dimethyl Occupational Exposures to component
-1,3-propanediyl)b Chemical Agents has not been
is(oxymethylene)] classified by
International
Agency for
Research on
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
Sensitisation : Skin sensitiser.
Mutagenicity : Neopentyl Glycol Diglycidyl ether (NPGDGE) was positive in
bacterial genetic toxicity assays.
: Mixed results were seen in mammalian toxicity assays.
Potential Health Effects
Inhalation : Not expected to be a relevant route of exposure, however,
under conditions where exposure to vapors or mists is possible,
could cause respiratory tract irritation.
Skin : May be mildly irritating to the skin.
May cause skin sensitization.
Prolonged or repeated skin contact can cause defatting and
drying of the skin which may result in a burning sensation and a
dried, cracked appearance.
Eyes : May be mildly irritating to the eyes.
SECTION 12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Biodegradability : This section will be updated as ecological reviews are
completed.
Ecotoxicity effects
Toxicity to fish : This section will be updated as ecological reviews are
completed.
SECTION 13. DISPOSAL CONSIDERATIONS
Product disposal : If this material becomes a waste, it would not be a hazardous
waste by RCRA criteria (40 CFR 261). Place in an appropriate
disposal facility in compliance with local and federal regulations.
SECTION 14. TRANSPORT INFORMATION
NOT REGULATED FOR TRANSPORT
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
NOT REGULATED FOR TRANSPORT
NOT REGULATED FOR TRANSPORT
SECTION 15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Notification status
INV (CN) : y
ENCS (JP) : y
EINECS : y
KECI (KR) : y
PICCS (PH) : y
y = Yes (Listed); AICS = Australian Inventory of Chemical
Notification status
S DSL = Canadian Domestic Substances L
INV(CN) = Inventory of Existing Chemicals Substances in
C ENCS(JP) = Japanese Existing and New Chemical
S TSCA = Toxic Substance Control A EINECS =
European Inventory of New and Existing C KECI(KR)
= Korean Existing Chemicals I PICCS(PH) = Philippine
Inventory of Chemicals and Chemical Substances
US. EPA CERCLA Hazardous Substances (40 CFR 302)
Oxirane, No RQ
2,2'-[(2,2-dimethyl-1,3-propanediyl)bi
s(oxymethylene)]bis-
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals(40 CFR 372. 65) - Supplier Notification Required
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
Oxirane, No De minimis Concentration
2,2'-[(2,2-dimethyl-1,3-propanediyl)bi
s(oxymethylene)]bis-
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
Oxirane, Threshold Planning Quantity: No TPQ
2,2'-[(2,2-dimethyl-1,3-propanediyl)bi
s(oxymethylene)]bis-
Oxirane, Reportable quantity: No RQ
2,2'-[(2,2-dimethyl-1,3-propanediyl)bi
s(oxymethylene)]bis-
New Jersey Right-To-Know Chemical List
Oxirane, Not Listed
2,2'-[(2,2-dimethyl-1,3-propanediyl)bis
(oxymethylene)]bis-
Additional Components Not Found In Section 2:
Components CAS-No. Concentration Remarks
1-chloro-2,3-epoxy propane 106-89-8 & 10 PPM Listed.
Pennsylvania Right-To-Know Chemical List
Oxirane, Not Listed
2,2'-[(2,2-dimethyl-1,3-propanediyl)bis
(oxymethylene)]bis-
Additional Components Not Found In Section 2:
Components CAS-No. Concentration Remarks
1-chloro-2,3-epoxy propane 106-89-8 & 10 PPM Special hazard.
Massachusetts Right-To-Know Chemical List
Oxirane, Not Listed
2,2'-[(2,2-dimethyl-1,3-propanediyl)bis
(oxymethylene)]bis-
Additional Components Not Found In Section 2:
Components CAS-No. Concentration Remarks
1-chloro-2,3-epoxy propane 106-89-8 & 10 PPM Carcinogenic.
Material Safety Data Sheet
HELOXY?? Modifier 68
Version 6.1 Print Date 07/06/2007
Revision Date 06/03/2007
US. California Safe drinking water & Toxic Enfor cement Act (Proposition 65)
Additional Components Not Found In Section 2:
Components Concentration Regulation Value Remarks
1-chloro-2,3-epox & 10 PPM US. California Safe Drinking Listed: Carcinogenic.
y propane Water & Toxic Enfor cement October 1,
Act (Proposition 65) 1987
HMIS Rating : Health: 2
Reactivity: 0
SECTION 16. OTHER INFORMATION
Reference : Prepared in accordance with 29 CFR .
Reference : This safety datasheet complies with the requirements of
Regulation (EC) No .
The information provided herein was believed by Hexion Specialty Chemicals (&Hexion&) to be accurate at the
time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to
investigate and understand other pertinent sources of information, to comply with all laws and procedures
applicable to the safe handling and use of the product and to determine the suitability of the product for its
intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION
MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF
ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications.
Nothing contained herein constitutes an offer for the sale of any product.
and Licensed trademarks of Hexion Specialty Chemicals, Inc.
A vertical bar ( | ) in the left margin indicates an amendment from the previous version.
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